If the Item is condition enabled, you'll want to make your INVVENDOR entries to include the Condition Code, e.g. I can buy the Widget from VendorX for $20 in NEW condition, or $15 in PREOWNED condition.
The CONDITIONCODE field exists on the INVVENDOR table, as you said, so just go into Application Designer and add it to the GUI, wherever needed -- Item Master, Tools, Inventory, Stocked Tools, Receiving, Purchase Orders, Purchase Requisitions, Materials Requisitions, Invoices, maybe others too.
You shouldn't want to disable the functionality. If you're spending the extra effort to make the Item condition enabled and configuring the available conditions for that item, then when you buy that item you'd need to also know the condition. This has ramifications for how much it costs, how it affects your inventory average costs, the quantity you have in-stock in any of the available conditions, the cost that is charged to a Work Order when you use that item, etc.